Synthesis, characterization and polymerization of acetylacetate, acetylacetamide or acetylacetanilide substituted cyclic imino ethers, new metal chelating monomers and polymers.
Bm. Culbertson et Yh. Tong, Synthesis, characterization and polymerization of acetylacetate, acetylacetamide or acetylacetanilide substituted cyclic imino ethers, new metal chelating monomers and polymers., MACRO SYMP, 156, 2000, pp. 253-261
New cyclic imino ether monomers, functionalized with acetylacetoxy, acetyla
cetamide, or acetylacetanilide moieties are described for the first time. T
hese monomers readily form metal complexes. Also, it is shown that these mo
nomers may be cationically homo- or copolymerized with other cyclic imino e
thers, to provide polymers having metal complexing ability. The monomers ha
ve potential applications in a wide variety of applications.