The experimental, determination of the low-lying rovibrational energy level
s of H-3(+) using high-resolution, high-sensitivity infrared laser spectros
copy has confirmed this ion's equilateral triangle equilibrium geometry, pr
ovided direct information on its quantum mechanical characteristics, and en
abled its extensive study in planetary ionospheres and in the interstellar
medium.
Since the discovery of the nu(2) <-- 0 fundamental band, the laboratory spe
ctroscopy of H-3(+) has been pushed to higher energies through the study of
vibrational hot bands, overtones, forbidden bands and combination bands. W
e review the 20 years of laboratory spectroscopy of this important ion, dis
cuss our recent work on the nu(1) + 2 nu(2)(2) <-- 0 and 2 nu(1) + nu(2) <-
- 0 bands, and examine the prospects for the future of H-3(+) spectroscopy.