Mv. Ryabkov et al., Thermodynamic properties of hyperbranched poly(methyldiallylsilane) in thetemperature range 0-340 K, POLYM SCI A, 42(9), 2000, pp. 1012-1016
For hyperbranched poly(methyldiallylsilane), the temperature dependence of
heat capacity was measured by adiabatic vacuum calorimetry in the temperatu
re range 5-340 K with an error of 0.2%, and the parameters of glass transit
ion and glass transition state were determined. Based on the experimental e
vidence, the thermodynamic functions C-p(o)(T), H degrees(T) - H degrees(0)
, S degrees(T), and G degrees(T) - H degrees(0) were calculated in the rang
e 0-340 K.