Thermodynamic properties of hyperbranched poly(methyldiallylsilane) in thetemperature range 0-340 K

Citation
Mv. Ryabkov et al., Thermodynamic properties of hyperbranched poly(methyldiallylsilane) in thetemperature range 0-340 K, POLYM SCI A, 42(9), 2000, pp. 1012-1016
Citations number
32
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMER SCIENCE SERIES A
ISSN journal
0965545X → ACNP
Volume
42
Issue
9
Year of publication
2000
Pages
1012 - 1016
Database
ISI
SICI code
0965-545X(200009)42:9<1012:TPOHPI>2.0.ZU;2-#
Abstract
For hyperbranched poly(methyldiallylsilane), the temperature dependence of heat capacity was measured by adiabatic vacuum calorimetry in the temperatu re range 5-340 K with an error of 0.2%, and the parameters of glass transit ion and glass transition state were determined. Based on the experimental e vidence, the thermodynamic functions C-p(o)(T), H degrees(T) - H degrees(0) , S degrees(T), and G degrees(T) - H degrees(0) were calculated in the rang e 0-340 K.