Dependence of the molecular mass characteristics and the thermal stability
of PMMA on the ferrocene content in a polymerizing system was studied. The
effect of ferrocene on the molecular mass of PMMA is governed by the nature
of the polymerization initiator. The addition of ferrocene does not signif
icantly change the molecular mass of the obtained polymer when AIBN used as
the initiator, but causes a sharp decrease in M-w and M-n for MMA polymeri
zation initiated by benzoyl peroxide. For PMMA obtained in the presence of
benzoyl peroxide, the degradation onset temperature and the molecular mass
vary in opposite directions.