Synthesis and properties of mixed oxides M(5)A(0.5)Zr(1.5)(MoO4)(6) (M = K, Tl)

Authors
Bazarov, BG Klevtsova, RF Bazarova, ZG Solodovnikov, SF Bazarova, ST Fedorov, KN
Citation
Bg. Bazarov et al., Synthesis and properties of mixed oxides M(5)A(0.5)Zr(1.5)(MoO4)(6) (M = K, Tl), RUSS J IN C, 45(9), 2000, pp. 1327-1330
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
45
Issue
9
Year of publication
2000
Pages
1327 - 1330
Database
ISI
SICI code
0036-0236(200009)45:9<1327:SAPOMO>2.0.ZU;2-P
Abstract
The subsolidus regions of the K2MoO4-AMoO(4)-Zr(MoO4)(2) (A = Ni, Co, Cu, Z n) and Tl2MoO4-AMoO(4)-Zr(MoO4)(2) (A = Mg, Mn, Ni, Co, Cu, Zn, Cd) systems were investigated for the first time using X-ray powder diffraction and di fferential thermal analyses. The formation of 5 : 1 : 3 and 1 : 1 : 1 inter mediate phases is characteristic of these systems. It was found that all of the divalent metals studied (Mg, Mn, Ni, Co, Cu, Zn, Cd) form 5 : 1 : 3 tr iple molybdates. The crystal, thermal, and electrophysical characteristics of the 5 : 1 : 3 phases obtained were determined.