Material innovations are reviewed within the context of ongoing biomechanic
al developments that relate the critical contact angle of second-order angu
lation (theta(c)) to the overall resistance to sliding (RS). As a science i
n its embryonic stage of development, RS is partitioned into classical fric
tion (FR), elastic binding (BI), and physical notching (NO). Both FR and BI
are defined in terms of normal forces (N) and kinetic coefficients (mu(k))
. The angulation at which NO occurs (theta(z)) is introduced as a second bo
undary condition to theta(c). Given this scientific backdrop, material modi
fications are sought that reduce RS. Approaches include minimizing mu(k) or
N within the context of FR and theta < theta(c), as, for example, by surfa
ce modifications of archwires and brackets or by engineering novel ligation
materials. Stabilizing theta at theta approximate to theta(c) should provi
de more efficient and effective sliding mechanics by developing innovative
materials (eg, composites) in which stiffness (EI) varies without changing
wire or bracket dimensions. Between the boundaries of theta(c) and theta(z)
(ie, theta(c) < theta < theta(z)), BI may be reduced by decreasing EI or i
ncreasing interbracket distance (IBD), independent of whether a conventiona
l or composite material is used.