The crystal structure of triphenylmethane-piperidine-sulfenamide

Authors
Brito, I Leon, Y Gacitua, C Arias, M Ponce, J Wittke, O Lopez-Rodriguez, I
Citation
I. Brito et al., The crystal structure of triphenylmethane-piperidine-sulfenamide, BOL SOC CH, 45(3), 2000, pp. 509-513
Citations number
17
Categorie Soggetti
Chemistry
Journal title
BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA
ISSN journal
03661644 → ACNP
Volume
45
Issue
3
Year of publication
2000
Pages
509 - 513
Database
ISI
SICI code
0366-1644(200009)45:3<509:TCSOT>2.0.ZU;2-R
Abstract
The crystal structure of triphenylmethane-piperidine-sulfenamide, C24H25NS is described and compared with other sulfenamides and with other similar co mpounds. This structure belongs to a type of divalent sulphur compound and crystallized in the triclinic system, space group P1 with a= 8.924(2), b=12 .541(3), c=17.813(3) Angstrom, alpha =90.09(2), beta= 93.07(2) rho= 90.41(2 ) degrees and Dr =1.20 g cm(-3) with Z=4. The S-N bond distance of 1.695(4) Angstrom is shorter than a single S-N bond [1.74 Angstrom].