The "trivial" mechanism for the photo-fries reaction of phenyl acetate andbiphenylyl acetates

Authors
Yoon, HJ Ko, SH Ko, MK Chae, WK
Citation
Hj. Yoon et al., The "trivial" mechanism for the photo-fries reaction of phenyl acetate andbiphenylyl acetates, B KOR CHEM, 21(9), 2000, pp. 901-904
Citations number
8
Categorie Soggetti
Chemistry
Journal title
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
ISSN journal
02532964 → ACNP
Volume
21
Issue
9
Year of publication
2000
Pages
901 - 904
Database
ISI
SICI code
0253-2964(20000920)21:9<901:T"MFTP>2.0.ZU;2-A
Abstract
The mechanism for the photo-Fries rearrangement of phenyl acetate and biphe nylyl acetates were reinvestigated in phenol (or phenol derivatives) contai ning media. The results showed that the phenol (or phenol derivatives) whic h is the most common by-product of Fries reaction reacts with acyl radical to give Fries-product. These phenol (or phenol derivatives) contributions t o the Fries-products were suggested as the Trivial mechanism for the photo- Fries reaction.