Remarkable cumulative stereoselectivity in cyclopropanation with supramolecular Cu(I) catalytic complexes

Authors
Portada, T Roje, M Raza, Z Caplar, V Zinic, M Sunjic, V
Citation
T. Portada et al., Remarkable cumulative stereoselectivity in cyclopropanation with supramolecular Cu(I) catalytic complexes, CHEM COMMUN, (20), 2000, pp. 1993-1994
Citations number
18
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
20
Year of publication
2000
Pages
1993 - 1994
Database
ISI
SICI code
1359-7345(2000):20<1993:RCSICW>2.0.ZU;2-E
Abstract
Supramolecular Cu(I) catalyst 1 exhibited 77% cumulative (dia- and enantio- ) stereoselectivity and one of the highest diastereoselectivities (86% de) obtained to date in the cyclopropanation of styrene with ethyl diazoacetate .