Synthesis and structural characterisation of the first hexaphosphastrontocene [Sr(eta(5)-P3C2Bu2t)(2)] and its pyrazine adduct

Authors
Francis, MD Hitchcock, PB Nixon, JF
Citation
Md. Francis et al., Synthesis and structural characterisation of the first hexaphosphastrontocene [Sr(eta(5)-P3C2Bu2t)(2)] and its pyrazine adduct, CHEM COMMUN, (20), 2000, pp. 2027-2028
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
20
Year of publication
2000
Pages
2027 - 2028
Database
ISI
SICI code
1359-7345(2000):20<2027:SASCOT>2.0.ZU;2-K
Abstract
Treatment of SrI2 with 2 equivalents of K[P3C2Bu2t] affords the hexaphospha strontocene [{Sr(eta(5)-P3C2Bu2t)(2)}(infinity)] which is polymeric in the solid state; treatment of this complex with an excess of pyrazine leads to the corresponding Lewis base adduct [{Sr(eta(5)-P3C2Bu2t)(2)(mu-C4H4N2)}(in finity)] which is also polymeric in the solid state.