Tandem 1,3-azaprotiocyclotransfer-cycloaddition reactions between aldoximes and divinyl ketone. Remarkable rate enhancement and control of cycloaddition regiochemistry by hafnium(IV) chloride

Authors
Dunn, PJ Graham, AB Grigg, R Higginson, P
Citation
Pj. Dunn et al., Tandem 1,3-azaprotiocyclotransfer-cycloaddition reactions between aldoximes and divinyl ketone. Remarkable rate enhancement and control of cycloaddition regiochemistry by hafnium(IV) chloride, CHEM COMMUN, (20), 2000, pp. 2035-2036
Citations number
11
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
20
Year of publication
2000
Pages
2035 - 2036
Database
ISI
SICI code
1359-7345(2000):20<2035:T1RBA>2.0.ZU;2-F
Abstract
The tandem 1,3-azaprotiocyclotransfer-cycloaddition reaction between aldoxi mes and divinyl ketone affords the exo- isomers of substituted 1-aza-8-oxab icyclo[3.2.1]octan-4-ones when a substoichiometric amount of hafnium(iv) ch loride is added.