We present a simple and general reduction algorithm for stiff monomolecular
kinetic systems. The reduction is based on algebraic techniques and consis
ts in eliminating the fastest dynamics in the initial system without any ch
ange of basis. This process is systematic and is not based on chemical conv
entional assumptions or on singular perturbation techniques. Systems can be
reduced even if they are not in the Tikhonov form. This reduction process
is applied to kinetic systems with kinetic constants belonging to different
scales. Error estimates for all species are given. Numerical tests are per
formed.