Citation
A. Weber et al., Structural investigations of tetra- and octasubstituted (phthalocyanine)ruthenium complexes by EXAFS spectroscopy, EUR J INORG, (10), 2000, pp. 2289-2294
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948
→ ACNP
Issue
10
Year of publication
2000
Pages
2289 - 2294
Database
ISI
SICI code
1434-1948(200010):10<2289:SIOTAO>2.0.ZU;2-G
Abstract
To obtain more structural information of (phthalocyaninato)-ruthenium compo
unds, an EXAFS investigation was carried out on amorphous tBu(4)PcRu (1), t
Bu(4)PcRu(3-Clpy)(2) (2), PcRu(3-Fpy)(2) (3) and (C5H11O)(8)PcRu(3-Clpy)(2)
(4). Structural models for the four compounds are deduced from the atomic
distances determined around the metal centre. A dimeric structure was found
for 1, while bisaxial arrangement of the ligands was shown for 2, 3 and 4,
and the structural parameters were also determined.