According to theoretical analysis, in ferroelectric ceramics internal field
s due to the screening of grain boundary depletion layers favours backward
switching of the spontaneous polarization after switching off the external
electric field Computer simulation shows that, in contrast to single crysta
ls, in ferroelectric ceramics with high enough density of grain boundary su
rface acceptor states, the electron emission may be observed repeatedly usi
ng the unipolar switching pulses.