A novel functionalized P,C,P pincer ligand complex

Authors
Grimm, JC Nachtigal, C Mack, HG Kaska, WC Mayer, HA
Citation
Jc. Grimm et al., A novel functionalized P,C,P pincer ligand complex, INORG CH C, 3(10), 2000, pp. 511-514
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
10
Year of publication
2000
Pages
511 - 514
Database
ISI
SICI code
1387-7003(200010)3:10<511:ANFPPL>2.0.ZU;2-F
Abstract
Reaction of 3,5-di(bromomethyl)nitrobenzene with di-t-butylphosphine and su bsequent treatment with sodium acetate gives the novel functionalized P,C,P pincer ligand 2. Heating an isopropanol/water solution of 2 with iridium(L II)chloride results in the iridium hydrochloride complex 3. This complex wa s characterized by X-ray structure analysis in the solid state, NMR spectro scopy in solution, and density functional calculations in the gas phase. (C ) 2000 Elsevier Science S.A. All rights reserved.