The formation of [RuCl(p-cymene)(Me(2)HPz)(PPh2OR)]Cl (Me(2)HPz=3,5-dimethylpyrazole; R = H, Me and p-Tol) complexes from the cleavage of the P-N bond of a P-coordinated P(Me(2)Pz)Ph-2 ligand by ROH molecules in a ruthenium(II) complex. Crystal structure of [RuCl(p-cymene)(Me(2)HPz)(PPh2OH)]Cl

Authors
Tribo, R Pons, J Yanez, R Piniella, JF Alvarez-Larena, A Ros, J
Citation
R. Tribo et al., The formation of [RuCl(p-cymene)(Me(2)HPz)(PPh2OR)]Cl (Me(2)HPz=3,5-dimethylpyrazole; R = H, Me and p-Tol) complexes from the cleavage of the P-N bond of a P-coordinated P(Me(2)Pz)Ph-2 ligand by ROH molecules in a ruthenium(II) complex. Crystal structure of [RuCl(p-cymene)(Me(2)HPz)(PPh2OH)]Cl, INORG CH C, 3(10), 2000, pp. 545-549
Citations number
35
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
10
Year of publication
2000
Pages
545 - 549
Database
ISI
SICI code
1387-7003(200010)3:10<545:TFO[(>2.0.ZU;2-E
Abstract
The complex [RuCl2(p-cymene)](2) reacts with 1-(3,5-dimethyl)pyrazolyldiphe nylphosphine (P(Me(2)Pz)Ph-2) to give the complex RuCl2(p-cymene)(P(Me(2)Pz )Ph-2). This compound reacts with ROH molecules (R = H, Me and p-Tol) to gi ve [RuCl(p-cymene)(Me(2)HPz)(PPh2OR)]Cl (R = H, Me and p-Tol) complexes, wh ich contain both Me(2)HPz and PPh2OR coordinated molecules. (C) 2000 Publis hed by Elsevier Science S.A.