The study reported here seeks to characterize behaviour of platinum electro
des of the 45-electrode spiral nerve cuff for selective electrical stimulat
ion of different superficial regions of peripheral nerves in physiological
solution (0.9% NaCl) and Eliott's buffered solution. Each electrode of the
spiral cuff had a flat geometric surface of 2 mm(2). To delineate an operat
ional potential window between hydrogen and oxygen evolution during stimula
tion the electrochemical technique of cyclic voltammetry was used. In a typ
ical cyclic voltammetry experiment, the potential of the tested electrode w
as cycled at an appropriate rate between two potential limits. The surfaces
of the electrodes, obtained after injection of the biphasic charge as defi
ned in a physiological solution (0.9% NaCl), thus simulating long-term elec
trical stimulation, were investigated using a high resolution Auger electro
n spectroscopy (AES) method.