Triangle distribution and equation of state for classical rigid disks

Citation
Dk. Stillinger et al., Triangle distribution and equation of state for classical rigid disks, J STAT PHYS, 100(1-2), 2000, pp. 49-72
Citations number
48
Categorie Soggetti
Physics
Journal title
JOURNAL OF STATISTICAL PHYSICS
ISSN journal
00224715 → ACNP
Volume
100
Issue
1-2
Year of publication
2000
Pages
49 - 72
Database
ISI
SICI code
0022-4715(200007)100:1-2<49:TDAEOS>2.0.ZU;2-2
Abstract
The triangle distribution function f((3)) for three mutual near neighbors i n the plane describes basic aspects of short-range order and statistical th ermodynamics in two-dimensional many-particle systems. This paper examines prospects for constructing a self-consistent calculation for the rigid-disk -system f((3)). Wr present several identities obeyed by f((3)). A rudimenta ry closure suggested by scaled-particle theory is introduced. In conjunctio n with three of the basic identities, this closure leads to an unique f((3) ) over the entire density range, The pressure equation of state exhibits qu alitatively correct behaviors in both the low-density and the close-packed limits, but no intervening phase transition appears. We discuss extensions to improved disk closures. and to the three-dimensional rigid-sphere system .