Kinetic arrest originating in competition between attractive interaction and packing force

Citation
G. Foffi et al., Kinetic arrest originating in competition between attractive interaction and packing force, J STAT PHYS, 100(1-2), 2000, pp. 363-376
Citations number
41
Categorie Soggetti
Physics
Journal title
JOURNAL OF STATISTICAL PHYSICS
ISSN journal
00224715 → ACNP
Volume
100
Issue
1-2
Year of publication
2000
Pages
363 - 376
Database
ISI
SICI code
0022-4715(200007)100:1-2<363:KAOICB>2.0.ZU;2-T
Abstract
We discuss the situation where attractive and repulsive portions of the int erparticle potential both contribute significantly to glass formation. We i ntroduce the square-well potential as prototypical model for this situation , and reject the Baxter model as a useful model for comparison to experimen t on glasses, based on our treatment within mode coupling theory. We presen t explicit results for various well widths, and show that, for narrow wells , there is a useful analytical formula that would be suitable for experimen talists working in the field of colloidal science. We raise the question as to whether, in a more exact treatment, the sticky-sphere limit might have an infinite glass transition temperature or a high but finite one.