Jg. Cheng et al., Effects of individual layer thickness on the structure and electrical properties of sol-gel-derived Ba0.8Sr0.2TiO3 thin films, J AM CERAM, 83(10), 2000, pp. 2616-2618
Ba0.8Sr0.2TiO3 thin films were prepared with various individual layer thick
nesses using a sol-gel process, The individual layer thickness strongly aff
ected the structure, ferroelectricity, and dielectric properties of the fil
ms, The films prepared with an individual layer thickness of 60 nm showed s
mall equiaxed grains, cubic structure, temperature-independent dielectric c
onstant, and no ferroelectricity, The films prepared with an individual lay
er thickness of 8 nm showed columnar grains, tetragonal structure, good fer
roelectricity, and two dielectric peaks in the dielectric constant-temperat
ure curve. The individual layer thickness for layer-by-layer homoepitaxy gr
owth that resulted in columnar grains was <20 nm.