Highly ordered size-dispersive packings of polydisperse microgel spheres

Dilute suspensions of polydisperse polystyrene microgels in the size range of 5-50 nm in organic solvents were evaporated under controlled conditions, and the resulting two-dimensional packing structures were investigated. Th e particles form highly ordered structures, as revealed by electron microsc opy. The ordering process is understood as a unique self-organization proce ss, in which differences in the particle size and the polydispersity of the particles are a main driving force. The structures follow the rules of hyp erbolic geometry and are named "Zenon"-packing, indicating that the two-dim ensional structures without translational invariance can still be understoo d as a special form of a regular lattice. A systematic variation of the sol vent quality and the surface tension of the suspension shows that the order ing essentially is based upon size-dispersive van der Waals attractions bet ween the microgels.