Enzymatically catalyzed synthesis of photocrosslinkable oligophenols

Authors
Reihmann, MH Ritter, H
Citation
Mh. Reihmann et H. Ritter, Enzymatically catalyzed synthesis of photocrosslinkable oligophenols, MACRO CH P, 201(14), 2000, pp. 1593-1597
Citations number
16
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULAR CHEMISTRY AND PHYSICS
ISSN journal
10221352 → ACNP
Volume
201
Issue
14
Year of publication
2000
Pages
1593 - 1597
Database
ISI
SICI code
1022-1352(20000928)201:14<1593:ECSOPO>2.0.ZU;2-#
Abstract
The HRP-catalyzed oligomerization of cinnamoyl-hydroquinone-ester and cinna moyl-4-hydroxyanilide led to the formation of soluble polyphenols. The olig omers were synthesized in water/1,4-dioxane and in water/actone mixtures an d characterized by NMR, FTIR and SEC. Upon UV-treatment of the treatment of the homogenous films films polyphenols were crosslinked due to [2+2]-cyclo additions of the cinnamoyl to functions.