Synthesis and characterization of new cardo polyamides and polyimides containing tert-butylcyclohexylidene units

A new cardo diamine monomer, 1.1-bis[4-(4-aminophenoxy)phenyl]-4-tert-butyl cyclohexane containing tert-butylcyclohexylidene units was prepared in thre e steps from 4-tert-butylcyclohexanone. The monomer was reacted with variou s aromatic dicarboxylic acids and tetracarboxylic dianhydrides to produce p olyamides and polyimides, respectively. All the, polymers, characterized by X-ray diffraction, are amorphous. These cardo polymers exhibit good solubi lity in a variety of solvents. Almost all polymers are soluble in N-methyl- 2-pyrrolidone (NMP), N,N-dimethylacetamide (DMAc), N,N-dimethylformamide (D MF), dimethyl sulfoxide (DMSO), pyridine, and even in tetrahydrofuran (THF) and cyclohexanone. The polymers show glass transition temperatures between 244-310 degrees C and decomposition temperatures at 10% mass loss ranging from 486-526 degrees C in nitrogen. The tough and flexible polymer films ha ve tensile strength of 77-137 MPa, elongations at breat of 5-14%, and tensi le moduli of 2.0-2.6 GPa.