H. Busemann et al., Primordial noble gases in "phase Q" in carbonaceous and ordinary chondrites studied by closed-system stepped etching, METEORIT PL, 35(5), 2000, pp. 949-973
The HF/HCl-resistant residues of the chondrites CM2 Cold Bokkeveld, CV3 (ox
.) Grosnaja, CO3.4 Lance, CO3.7 Isna, LL3.4 Chainpur, and H3.7 Dimmitt have
been measured by closed-system stepped etching (CSSE) in order to better c
haracterise the noble gases in "phase Q", a major carrier of primordial nob
le gases. All isotopic ratios in phase Q of the different meteorites are qu
ite uniform, except for (Ne-20/Ne-22)(Q). As already suggested by precise e
arlier measurements (Schelhaas et al., 1990; Wieler et al., 1991, 1992), (N
e-20/Ne-22)(Q) is the least uniform isotopic ratio of the Q noble gases. Th
e data cluster similar to 10.1 for Cold Bokkeveld and Lance and 10.7 for Ch
ainpur, Grosnaja, and Dimmitt, respectively. No correlation of (20Ne/22Ne)(
Q) with the classification or the alteration history of the meteorites has
been found. The Ar, Kr, and Xe isotopic ratios for all six samples are iden
tical within their uncertainties and similar to earlier Q determinations as
well as to Ar-Xe in ureilites. Thus, an unknown process probably accounts
for the alteration of the originally incorporated Ne-Q. The noble gas eleme
ntal compositions provide evidence that Q consists of at least two carbonac
eous carrier phases "Q(1)" and "Q(2)" with slightly distinct chemical prope
rties. Ratios (Ar/Xe)(Q) and (Kr/Xe)(Q) reflect both thermal metamorphism a
nd aqueous alteration. These parent-body processes have led to larger deple
tions of Ar and Kr relative to Xe. In contrast, meteorites that suffered se
vere aqueous alteration, such as the CM chondrites, do not show depletions
of He and Ne relative to Ar but rather the highest (He/Ar)(Q) and (Ne/Ar)(Q
) ratios. This suggests that Q(1) is less susceptible to aqueous alteration
than Q(2). Both subphases may well have incorporated noble gases from the
same reservoir, as indicated by the nearly constant, though very large, dep
letion of the lighter noble gases relative to solar abundances. However, th
e elemental ratios show that Q(1) and Q(2) must have acquired (or lost) nob
le gases in slightly different element proportions. Cold Bokkeveld suggests
that Q(1) may be related to presolar graphite. Phases Q(1) and Q(2) might
be related to the subphases that have been suggested by Gros and Anders (19
77). The distribution of the Ne-20/N-22 ratios cannot be attributed to the
carriers Q(1) and Q(2) The residues of Chainpur and Cold Bokkeveld contain
significant amounts of Ne-E(L), and the data confirm the suggestion of Huss
(1997) that the Ne-22-E(L) content, and thus the presolar graphite abundan
ces, are correlated with the metamorphic history of the meteorites.