Synthesis and characterization of novel iron(0) complexes derived from alpha,beta-unsaturated-ketone analogues with beta-positioned heteroatoms containing covalent and coordination bonds

Authors
Ortega-Jimenez, F Ortega-Alfaro, MC Lopez-Cortes, JG Gutierrez-Perez, R Toscano, RA Velasco-Ibarra, L Pena-Cabrera, E Alvarez-Toledano, C
Citation
F. Ortega-jimenez et al., Synthesis and characterization of novel iron(0) complexes derived from alpha,beta-unsaturated-ketone analogues with beta-positioned heteroatoms containing covalent and coordination bonds, ORGANOMETAL, 19(20), 2000, pp. 4127-4133
Citations number
23
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
19
Issue
20
Year of publication
2000
Pages
4127 - 4133
Database
ISI
SICI code
0276-7333(20001002)19:20<4127:SACONI>2.0.ZU;2-O
Abstract
Synthesis of novel mono- and dinuclear complexes of Fe(0) are reported disp laying both coordination and organometallic bonds. 5-11 were prepared by al lowing the new ligands 1-4 to react with Fe-2(CO)(9). The structures of the complexes were determined by spectroscopic methods (IR, MS, HR-MS, H-1 and C-13 NMR) and confirmed by single-crystal X-ray analysis.