Sulfido-bridged titanium-iridium heterobimetallic complexes derived from an iridium hydrosulfido complex

Authors
Nagano, T Kuwata, S Ishii, Y Hidai, M
Citation
T. Nagano et al., Sulfido-bridged titanium-iridium heterobimetallic complexes derived from an iridium hydrosulfido complex, ORGANOMETAL, 19(20), 2000, pp. 4176-4178
Citations number
40
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
19
Issue
20
Year of publication
2000
Pages
4176 - 4178
Database
ISI
SICI code
0276-7333(20001002)19:20<4176:STHCDF>2.0.ZU;2-3
Abstract
Reactions of [Cp*Ir(SH)(2)(PMe3)] (1; Cp* = eta(5)-C5Me5) with [CpTiCl3](Cp = eta(5)-C5H5) and [TiCl4(thf)(2)] in the presence of triethylamine afford ed the sulfido-bridged titanium-iridium heterobimetallic complexes [CpTiCl( mu(2)-S)(2)Ir-(PMe3)Cp*] (2) and [TiCl2(mu(2)-S)(2)Ir(PMe3)Cp*] (3), respec tively.