Tracer diffusion and the isotope effect in the binary random alloy

In this paper the correlation factors, as obtained from the ratio of tracer diffusion coefficients in the binary random alloy model, are compared with the correlation factors as would be obtained from isotope effect measureme nts. In this context, two theories, one due to Manning, the other due to Mo leko, Allnatt and Allnatt are examined in detail. We show that for both ato mic components Manning's theory (where both types of correlation factors ar e automatically equal) gives reasonable agreement with Monte Carlo data onl y when the tracer diffusion coefficients are within a factor of two. On the other hand, the theory of Moleko ct nl. gives excellent agreement for both correlation factors over a very wide range of diffusion coefficient ratios . To demonstrate some of these differences the formalisms of Manning and Mo leko ct al. are applied to the Fe-Co and Cu-Zn systems.