Spectrally resolved photoconductivity (PC) experiments on homoepitaxially g
rown, Li doped chemical vapour deposited diamond layers are presented. Om m
easurements reveal two new photoconductive levels with absorption threshold
s at photon energies of 0.9 eV and 1.5 eV. Due to metastable occupation, th
e spectral dependence of the photoconductivity exhibits a pronounced peak.
Via photoconductivity excitation experiments it could be shown that both ne
w levels can be filled by photoionisation of the N donor. No correlation be
tween Li content and spectral weight of photoexcitation at 1.7 eV could be
observed.