We measured time and spectrally reserved, resonantly and nonresonantly exci
ted photoluminescence of self assembled vertically aligned InP/(GaIn)P quan
tum dots on GaAs substrates with various spacer thicknesses (2, 4, 8, and 1
6 nm) between the dot layers. The different interdot coupling in the variou
s structures leads to considerable differences in the electron relaxation p
rocess. Carriers tunnel in the vertically aligned dot stacks to the lowest
energy state when the spacer thickness is small, resulting in a pronounced
red shift and slowing down of the photoluminescence decay. We present simpl
e models to explain the results of our measurements.