Dielectric, acoustic, densimetric and viscosimetric investigations of the tributylamine plus propionic acid system

Citation
K. Orzechowski et al., Dielectric, acoustic, densimetric and viscosimetric investigations of the tributylamine plus propionic acid system, PHYS CHEM P, 2(20), 2000, pp. 4676-4681
Citations number
34
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
2
Issue
20
Year of publication
2000
Pages
4676 - 4681
Database
ISI
SICI code
1463-9076(2000)2:20<4676:DADAVI>2.0.ZU;2-#
Abstract
Data obtained at 293 K and atmospheric pressure by different experimental t echniques, dielectric, acoustic, densimetric and viscosimetric, give an alm ost uniform picture of the structure of the investigated binary mixture. Th e extrema observed at the concentration range 70-75 mol% of propionic acid are explained as a result of the formation of amine-acid associates of comp osition 1:n where n approximate to 3. Analysis of the dielectric relaxation parameters suggests a high flexibility of these associates.