-[2,3-BIS(METHYLTHIO)HEXANE-S,S']DICHLOROZINC(II), 2-BIS(METHYLTHIO)CYCLOHEXANE-S,S']DICHLOROZINC(II) AND HYLTHIO)-1,3-CYCLOHEPTADIENE-S,S']DICHLOROZINC(II)

Authors
PARVEZ M MESHER STE CLARK PD
Citation
M. Parvez et al., -[2,3-BIS(METHYLTHIO)HEXANE-S,S']DICHLOROZINC(II), 2-BIS(METHYLTHIO)CYCLOHEXANE-S,S']DICHLOROZINC(II) AND HYLTHIO)-1,3-CYCLOHEPTADIENE-S,S']DICHLOROZINC(II), Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 681-685
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
6
Pages
681 - 685
Database
ISI
SICI code
0108-2701(1997)53:<681:-2>2.0.ZU;2-8
Abstract
The crystal structures of [2,3-bis(methylthio)-hexane-S,S']dichlorozin c(II), [ZnCl2(C8H18S2)], trans[1,2-bis(methylthio) cyclohexane-S,S']di chlorozinc(II), [ZnCl2(C8H16S2)], and ylthio)-1,3-cycloheptadiene-S,S' ]dichlorozinc(II), [ZnCl2(C9H14S2)], contain distorted tetrahedral Zn atoms coordinated to two Cl and two S atoms, with Zn-Cl and Zn-S dista nces in the ranges 2.190(2)-2.222(2) and 2.369(2)-2.475(1) Angstrom, r espectively. The Cl-Zn-Cl and S-Zn-S angles in the three compounds are in the ranges 117.35(4)-122.63(4) and 88.11(5)-91.12(6)degrees, respe ctively.