HYDRIDO-3-RHODA-CLOSO-DODECABORANE-DICHLOROMETHANE (1 1)/

Authors
MCENEANEY PA SPALDING TR MEEHAN PR FERGUSON G
Citation
Pa. Mceneaney et al., HYDRIDO-3-RHODA-CLOSO-DODECABORANE-DICHLOROMETHANE (1 1)/, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 685-687
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
6
Pages
685 - 687
Database
ISI
SICI code
0108-2701(1997)53:<685:H(1>2.0.ZU;2-Z
Abstract
In the title complex, [RhH(C2B9H9Br2)(C18H15P)2]. CH2Cl2, the rhodacar borane molecule adopts a closed icosahedral RhC2B9-cage geometry with adjacent Rh and C atoms. Principal distances include Rh-P 2.345 (2) an d 2.276 (2), Rh-C 2.289 (8) and 2.241 (8), and B-Br 1.974 (9) and 1.98 0 (9) Angstrom.