A CYCLOBORONATED NICKELAUNDECABORANE - [(PHCOS)(2)NIB10H8(PPH3)]

Authors
DOU JM HU CH YAO HJ LI W JIN RS ZHENG PJ
Citation
Jm. Dou et al., A CYCLOBORONATED NICKELAUNDECABORANE - [(PHCOS)(2)NIB10H8(PPH3)], Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 693-695
Citations number
19
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
6
Pages
693 - 695
Database
ISI
SICI code
0108-2701(1997)53:<693:ACN-[>2.0.ZU;2-K
Abstract
The title compound di(mu-thiobenzoato-S:O)-10(triphenylphosphine-P)-8 :9-mu H-7-nickela-nido-undecaborane, C32H33B10NiO2PS2, has been synthe sized and characterized by X-ray diffraction analysis. The cluster is a nido eleven-vertex {NiB10} cage with the Ni atom in the open NiB4 fa ce. Cyclizations resulting in two five-membered rings, Ni7-S1-C1-O1-B8 and Ni7-S2-C2-O2--B11, have occurred.