-BIPHENYLCARBOXYLATO-O-O')BIS-[CHLORORHENIUM(III)] BIS(DICHLOROMETHANE) SOLVATE

Authors
COTTON FA DANIELS LM LU J REN T
Citation
Fa. Cotton et al., -BIPHENYLCARBOXYLATO-O-O')BIS-[CHLORORHENIUM(III)] BIS(DICHLOROMETHANE) SOLVATE, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 714-716
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
6
Pages
714 - 716
Database
ISI
SICI code
0108-2701(1997)53:<714:-B>2.0.ZU;2-Z
Abstract
The title complex, [Re2Cl2(C13H9O2)(4)]. 2CH(2)Cl(2), has the well kno wn 'paddle-wheel' structure common in many M-2(O2CR)(4) structures and the Cl ligands occupy the axial positions. The Re atoms are joined by a quadruple bond of length 2.2363(7) Angstrom and each metal atom is in a pseudo-octahedral environment. The molecule contains an inversion centre and two ortho-phenyl groups of the carboxylate ligands extend out over each axial region.