Influence of capillary condensation on the near-critical solvation force

Citation
A. Drzewinski et al., Influence of capillary condensation on the near-critical solvation force, PHYS REV L, 85(15), 2000, pp. 3079-3082
Citations number
29
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW LETTERS
ISSN journal
00319007 → ACNP
Volume
85
Issue
15
Year of publication
2000
Pages
3079 - 3082
Database
ISI
SICI code
0031-9007(20001009)85:15<3079:IOCCOT>2.0.ZU;2-U
Abstract
We argue that in a fluid, or magnet, confined by adsorbing walls which favo r liquid, or the (+) phase, the solvation (Casimir) force in the vicinity o f the critical point is strongly influenced by capillary condensation which occurs below the bulk critical temperature T-c. At T slightly below and ab ove T-c, a small bulk field h < 0, which favors gas, or the (-) phase, lead s to residual condensation and a solvation force which is much more attract ive (at the same large wall separation) than that found exactly at the crit ical point. Our predictions are supported by results obtained from density- matrix renormalization-group calculations in a two-dimensional Ising strip subject to identical surface fields.