(2,2'-BIPYRIDINE-N,N')(MU-THIOSULFATO)-CADMIUM(II)

Authors
BAGGIO S PARDO MI BAGGIO R GARLAND MT
Citation
S. Baggio et al., (2,2'-BIPYRIDINE-N,N')(MU-THIOSULFATO)-CADMIUM(II), Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 727-729
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
6
Pages
727 - 729
Database
ISI
SICI code
0108-2701(1997)53:<727:(>2.0.ZU;2-E
Abstract
The title Cd-II complex, [Cd(S2O3)(C10H8N2)], consists of polymeric ch ains running along the monoclinic symmetry axis. The elementary units are defined by pentacoordinated Cd-II atoms bonded to three different thiosulfate groups and a bidentate bipyridine ligand. The bridging thi osulfates bind metal centres through two different sequences, Cd1-S1-C d1' and Cd1-O1'-S2'-S1'-Cd1', thus defining a six-membered ring. Indiv idual chains are held together solely via van der Waals interactions.