Synthesis and characterization of a new molecular magnet, [Ni(ampy)(2)](3)[Fe(CN)(6)](2)center dot 6H(2)O, and synthesis, crystal structure and magnetic properties of its mononuclear precursor, trans-[Ni(ampy)(2)(NO3)(2)] (ampy=2-aminomethylpyridine)
S. Tanase et al., Synthesis and characterization of a new molecular magnet, [Ni(ampy)(2)](3)[Fe(CN)(6)](2)center dot 6H(2)O, and synthesis, crystal structure and magnetic properties of its mononuclear precursor, trans-[Ni(ampy)(2)(NO3)(2)] (ampy=2-aminomethylpyridine), POLYHEDRON, 19(16-17), 2000, pp. 1967-1973
The reaction of trans-[Ni(ampy)(2)(NO3)(2)] (1) (ampy = 2-aminomethylpyridi
ne) with K-3[Fe(CN)(6)] affords a cyano-bridged bimetallic system, (Ni(ampy
)(2)](3)[Fe(CN)(6)](2). 6H(2)O (2). The crystal structure of compound 1 has
been solved. It crystallizes in the monoclinic space group P121/c1 and con
sists of neutral mononuclear entities with the nickel atom located on an in
version center. The nickel atom exhibits a (pseudo)octahedral stereochemist
ry with the two nitrate ligands coordinated in trans positions. The Ni-N bo
nd distances vary from 2.0690(15) to 2.0811(15) Angstrom, while the trans-N
i-O distances are 2.1665(13) Angstrom. The cryomagnetic investigation of co
mpound 1 reveals an intermolecular ferromagnetic coupling (theta = + 3.7 K)
, which is mediated by the pi-pi stacking interactions between the mononucl
ear entities. Compound 2 is a soft ferromagnet with T-c = 7.5 K and a coerc
ive field of 330 G at 2 K. (C) 2000 Elsevier Science Ltd. All rights reserv
ed.