The thermodynamic characteristics of solvation of macroheterorings with thiadiazole fragments in organic solvents

Citation
Gr. Berezina et al., The thermodynamic characteristics of solvation of macroheterorings with thiadiazole fragments in organic solvents, RUSS J PH C, 74(10), 2000, pp. 1616-1619
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
74
Issue
10
Year of publication
2000
Pages
1616 - 1619
Database
ISI
SICI code
0036-0244(200010)74:10<1616:TTCOSO>2.0.ZU;2-A
Abstract
New data on the solubility of macroheterocyclic compounds containing indand ione-1,3, thiadiazole, benzene, and pyridine fragments in alcohols and tetr achloromethane at 288-308 K were obtained. The thermodynamic parameters of solution of such heterocyclic compounds in an aprotic solvent and alcohols were calculated. The solubilities in tetrachloromethane were an order of ma gnitude lower than in alcohols, and the corresponding Delta S degrees value s were also smaller.