1,2-diaza-1,3-butadienes as powerful tools in the synthesis of new 1,6-dithia-4,9-diazaspiro[4.4]non-2-enes and 1-oxa-6-thia-4,9-diazaspiro[4.4]non-7-enes
A. Arcadi et al., 1,2-diaza-1,3-butadienes as powerful tools in the synthesis of new 1,6-dithia-4,9-diazaspiro[4.4]non-2-enes and 1-oxa-6-thia-4,9-diazaspiro[4.4]non-7-enes, SYNLETT, (10), 2000, pp. 1464-1466
1,2-Diaza-1,3-butadienes react with 2-mercapto-2-thiazoline to give 1,4-add
ucts that in turn produce new 1,6-dithia-4,9-diazaspiro[4.4]non-2-ene deriv
atives. The same reactants treated with oxazolidine-2-thione directly affor
d new 1-oxa-6-thia-4,9-diazaspiro[4.4]non-7-ene derivatives.