Direct vinylation of cholesterol with acetylene

Citation
Ba. Trofimov et al., Direct vinylation of cholesterol with acetylene, SYNTHESIS-S, (11), 2000, pp. 1521-1522
Citations number
11
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
SYNTHESIS-STUTTGART
ISSN journal
00397881 → ACNP
Issue
11
Year of publication
2000
Pages
1521 - 1522
Database
ISI
SICI code
0039-7881(200010):11<1521:DVOCWA>2.0.ZU;2-P
Abstract
Delta(5)-Cholesten-3 beta-ol reacts with acetylene in the system KOH/DMSO t o form 3 beta-vinyloxy-Delta(5)-cholestene in 90% preparative yield.