Crystal structural properties of a pinwheel compound: [3(6)](1,2,3,4,5,6)cyclophane

Authors
Yasutake, M Sakamoto, Y Onaka, S Sako, K Tatemitsu, H Shinmyozu, T
Citation
M. Yasutake et al., Crystal structural properties of a pinwheel compound: [3(6)](1,2,3,4,5,6)cyclophane, TETRAHEDR L, 41(41), 2000, pp. 7933-7938
Citations number
14
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
41
Year of publication
2000
Pages
7933 - 7938
Database
ISI
SICI code
0040-4039(20001007)41:41<7933:CSPOAP>2.0.ZU;2-Z
Abstract
In the crystal structures of [3(6)](1,2,3,4,5,6)cyclophane 1 and the 1:TCNQ (1:1) complex, the cyclophane moiety is observed as the D-6h structure bec ause of the disorder of the molecules with C-6h symmetry. In contrast, the C-6h structure is observed in the crystals of the 1:TCNQ-F-4 (1:1) complex, and the complex shows an alternating donor-acceptor stacking with partial donor-acceptor overlap. (C) 2000 Elsevier Science Ltd. All rights reserved.