Peat has been investigated by several researchers as a sorbent for the capt
ure of dissolved metals from wastestreams. Besides being plentiful and inex
pensive, pear possesses several characteristics that make it an effective m
edia for the removal of dissolved metal pollutants. The mechanism of metal
ion binding to peat remains a controversial area with ion-exchange, complex
ation, and surface adsorption being the prevalent theories. Factors affecti
ng adsorption include pH, loading rates, and the presence of competing meta
ls. The optimum pH range for metals capture is generally 3.5-6.5. Although
the presence of more than one metal in a solution creates competition For s
orption sites and less of a particular ion may be bound, the total sorption
capacity has been found to increase. Studies have also shown that metals r
emoval is most efficient when the loading rates are low. In addition, recov
ery of metals and regeneration of the peat is possible using acid elution w
ith little effect on peat's sorption capacity.
The utilization of peat and other biomass materials for the treatment of wa
stewater containing heavy metals is gaining more attention as a simple. eff
ective and economical means of pollution remediation. Pelleting processes c
an now produce a robust media for a variety of applications where tradition
al methods of pollutant removal would he economically or technologically di
fficult. (C) 2000 Elsevier Science Ltd. All rights reserved.