Psuedohalogeno metal compounds. LXXVII Structure of hexafulminatocobaltate(III), [Co(CNO)(6)](3-)

Authors
Mayer, P Ponikwar, W Feldl, K Swoboda, P Beck, W
Citation
P. Mayer et al., Psuedohalogeno metal compounds. LXXVII Structure of hexafulminatocobaltate(III), [Co(CNO)(6)](3-), Z ANORG A C, 626(10), 2000, pp. 2038-2039
Citations number
24
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
626
Issue
10
Year of publication
2000
Pages
2038 - 2039
Database
ISI
SICI code
0044-2313(200010)626:10<2038:PMCLSO>2.0.ZU;2-7
Abstract
In the crystal of [AsPh4](3)[Co(CNO)(6)] the hexafulminatocobstitate(III) a nion forms an ideal octahedron with linear C=N-O ligands and with relativel y short cobalt-carbon bonds (Co-C 191 pm), In the crystal the [AsPh4](+) ca tions ''dilute" the energy rich anions.