Crystal structure of di-mu(2)-chlorobis[bis(di-tert-butylphosphino)-methane]diiridium, C34H76Cl2Ir2P4 and of di-mu(2)-iodobis[bis(di-tert-butylphosphino)methane]diiridium, C34H76I2Ir2P4, two halide-bridged iridium dimers

Authors
Hofmann, P Meier, C Maier, A Steck, O Sporys, V Rominger, F
Citation
P. Hofmann et al., Crystal structure of di-mu(2)-chlorobis[bis(di-tert-butylphosphino)-methane]diiridium, C34H76Cl2Ir2P4 and of di-mu(2)-iodobis[bis(di-tert-butylphosphino)methane]diiridium, C34H76I2Ir2P4, two halide-bridged iridium dimers, Z KRIST-NEW, 215(4), 2000, pp. 609-614
Citations number
6
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES
ISSN journal
14337266 → ACNP
Volume
215
Issue
4
Year of publication
2000
Pages
609 - 614
Database
ISI
SICI code
1433-7266(2000)215:4<609:CSOD>2.0.ZU;2-2
Abstract
C34H76Cl2Ir2P4, monoclinic, P12(1)/c1 (No. 14), a = 16.8061(3) Angstrom, b = 13.0107(2) Angstrom, c = 21.4000(3) Angstrom, beta = 113.118(1)degrees, V = 4303.6 Angstrom(3), Z = 4, R-gt(F) = 0.053, wR(obs)(F-2) = 0.140, T = 20 0 K. C34H76I2Ir2P4, monoclinic, P12(1)/n1 (No. 14), a = 23.8048(3) Angstrom, b = 15.9520(3) Angstrom, c = 24.1559(5) Angstrom, beta = 107.084(1)degrees, V = 8768.2 Angstrom(3), Z = 8, R-gt(F) = 0.044, wR(ref)(F-2) = 0.075, T = 200 K.