A new type of automatic ellipsometer based on a phase-shifting techniq
ue is described, where an electrooptic modulator made of ADP (ammonium
dihydrogen phosphate) crystals is used for phase shifting; thus we ca
ll it the phase-shifting ellipsometer. The light source is a 5 mW He-N
e laser. The intensities changed as the phase retardation Gamma was sh
ifted by 0, pi/2 and pi. The design, alignment, and calibration of the
system are discussed in detail. Once the optical system is aligned, a
ll components are free from mechanical movement, hence the precision i
s high. The accuracy of the results has been evaluated, and the errors
introduced on Psi and Delta are <0.032 degrees and 0.19 degrees, resp
ectively. The inaccuracy of the phase shift can only introduce an erro
r on Delta, and the degree of error on Delta is the same as that on Ga
mma, so it is very easily to modify.