Oxidation of N-benzyl groups

Authors
Qiu, WG Chen, SS Yu, YZ
Citation
Wg. Qiu et al., Oxidation of N-benzyl groups, CHIN J CHEM, 18(5), 2000, pp. 756-758
Citations number
23
Categorie Soggetti
Chemistry
Journal title
CHINESE JOURNAL OF CHEMISTRY
ISSN journal
1001604X → ACNP
Volume
18
Issue
5
Year of publication
2000
Pages
756 - 758
Database
ISI
SICI code
1001-604X(200009/10)18:5<756:OONG>2.0.ZU;2-O
Abstract
The oxidative reactivity of 2,6,8,12-tetraacetyl-4,10-dibenzyl-2,4,6,8,10,1 2-hexaazatetracyclo[5.5.0.0(5,9).0(3,11)] dodecane (3) in several condition s was studied. It was found that the N-benyl groups in compound 3 could be oxidized to benzoyl groups by Cr(VI) reagents, and could be removed by ceri um ammonium nitrate (CAN), meanwhile nitroamine products were given.