Syntheses and molecular self-assembly of chiral phosphoramidates

Authors
Du, DM Hua, WT Wang, JW Jin, XL
Citation
Dm. Du et al., Syntheses and molecular self-assembly of chiral phosphoramidates, CHIN J CHEM, 18(5), 2000, pp. 764-769
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHINESE JOURNAL OF CHEMISTRY
ISSN journal
1001604X → ACNP
Volume
18
Issue
5
Year of publication
2000
Pages
764 - 769
Database
ISI
SICI code
1001-604X(200009/10)18:5<764:SAMSOC>2.0.ZU;2-3
Abstract
Two chiral phosphoramidates, (R)-(-)-1,1'-binaphthyl-2,2'-dihydroxy-N-[alph a-(S)-methylbenzyl]phosphoramidate and (-)-1,1'-biphenyl-2,2'-dihydroxy-N-[ alpha-(S)-methylbenzyl]phosphoramidate were synthesized. Their crystal stru ctures were determined by X-ray single crystal diffraction analysis. The ph osphoramidate molecules are self-associated by intermolecular N-H ... O=P h ydrogen bonds and aromatic edge to face interactions.