ZINCA-ENE-ALLENE CYCLIZATIONS - A WAY TO SUBSTITUTED TETRAHYDROFURANSOR PYRROLIDINES

Citation
E. Lorthiois et al., ZINCA-ENE-ALLENE CYCLIZATIONS - A WAY TO SUBSTITUTED TETRAHYDROFURANSOR PYRROLIDINES, Bulletin de la Societe chimique de France, 134(3-4), 1997, pp. 333-341
Citations number
49
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
ISSN journal
00378968
Volume
134
Issue
3-4
Year of publication
1997
Pages
333 - 341
Database
ISI
SICI code
0037-8968(1997)134:3-4<333:ZC-AWT>2.0.ZU;2-L
Abstract
Polysubstituted enynes have been lithiated on the propargylic position , and transmetalation to the corresponding zinc reagents promotes an e asy cyclization reaction leading to polysubstituted tetrahydrofurans a nd pyrrolidines of definite geometry via the zinca-ene-allene reaction .