The equations of state of end-member MgSiO3, low-clinoenstatite and or
thoenstatite have been measured by single-crystal X ray diffraction to
pressures in excess of 8.5 GPa. The volume variation with pressure of
low-clinoenstatite (space group P2(1)/c) is described by a third-orde
r Birch-Murnaghan equation of state with the parameters V-0 = 31.292(8
) cm(3) mol(-1), K-T0= 111.1(3.3) GPa, and K-T0' 6.6(1.1). At pressure
s in excess of 7 GPa the low-clinoenstatite inverts to a high-clinoens
tatite phase (space group C2/c), with a volume reduction of 0.798(14)
cm(3)mol(-1). This transformation is reversible but with significant h
ysteresis at room temperature; the low-clinoenstatite is recovered on
decompression to below 5.3 GPa. The volume variation of orthoenstatite
(space group Pbca) displays a discontinuity at similar to 4 GPa which
corresponds to a change in the internal mechanism of compression. The
equations of state fitted to data below and above 4 GPa have the para
meters: P < 4 GPa, V-0 = 31.354(8) cm(3) mol(-1), K-T0 = 95.8(3.0) GPa
, and K-T0' = 14.9(2.0) and P > 4 GPa, V-0 = 31.23(10) cm(3) mol(-1),
K-T0 = 122.8(16.5) GPa, and K-T0' = 5.6(2.9). From these data, and the
slopes of the equilibrium phase boundaries, estimates of Delta S, Del
ta H, and Delta V of the transformations between the three enstatite p
olymorphs are calculated.