Demixing in binary mixtures of hard hyperspheres

Citation
Sb. Yuste et al., Demixing in binary mixtures of hard hyperspheres, EUROPH LETT, 52(2), 2000, pp. 158-164
Citations number
49
Categorie Soggetti
Physics
Journal title
EUROPHYSICS LETTERS
ISSN journal
02955075 → ACNP
Volume
52
Issue
2
Year of publication
2000
Pages
158 - 164
Database
ISI
SICI code
0295-5075(200010)52:2<158:DIBMOH>2.0.ZU;2-P
Abstract
The phase behavior of binary fluid mixtures of hard hyperspheres in four an d five dimensions is investigated. Spinodal instability is found by using a recent and accurate I,rescription for the equation of state of the mixture that requires the equation of state of the single component fluid as input . The role played by the dimensionality on the possible metastability of th e demixing transition with respect to a fluid-solid transition is discussed . The binodal curves in the pressure-chemical potential representation are seen to lie on a common line, independent of the size ratio.